AI Article Synopsis
- A single-walled carbon nanotube (SWNT) is formed from a single layer of graphene and requires topological defects to undergo plastic deformation.
- In situ high-resolution transmission electron microscopy (HR-TEM) has provided direct imaging of pentagon-heptagon pair defects in SWNTs heated to 2,273 K, previously unexamined in experiments.
- The findings indicate that these defects accumulate near deformed areas of the nanotube, supporting the theory that dislocation motions and topological defects contribute to the plastic deformation of SWNTs.
Article Abstract
A single-walled carbon nanotube (SWNT) is a wrapped single graphene layer, and its plastic deformation should require active topological defects--non-hexagonal carbon rings that can migrate along the nanotube wall. Although in situ transmission electron microscopy (TEM) has been used to examine the deformation of SWNTs, these studies deal only with diameter changes and no atomistic mechanism has been elucidated experimentally. Theory predicts that some topological defects can form through the Stone-Wales transformation in SWNTs under tension at 2,000 K, and could act as a dislocation core. We demonstrate here, by means of high-resolution (HR)-TEM with atomic sensitivity, the first direct imaging of pentagon-heptagon pair defects found in an SWNT that was heated at 2,273 K. Moreover, our in situ HR-TEM observation reveals an accumulation of topological defects near the kink of a deformed nanotube. This result suggests that dislocation motions or active topological defects are indeed responsible for the plastic deformation of SWNTs.
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| http://dx.doi.org/10.1038/nnano.2007.141 | DOI Listing |
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