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Exceptionally Strong Triply Dative Be-F Bonds in [CO]BeF and [CO]BeF Complexes: Reducing Valence Shell Electron Repulsion to Achieve High Bond Dissociation Energies.
Inorg Chem
January 2025
Institute of Atomic and Molecular Physics, Jilin University, Changchun 130023, China.
Dative bonds are typically polar, weaker, and longer than electron-sharing covalent bonds. The intriguing diatomic BeF anion uniquely exhibits triple Be-F dative bonding with a considerable bond dissociation energy (BDE) of 88 kcal/mol. Here, we report exceptionally strong dative-bonded systems, [CO]BeF and [CO]BeF, with BDE values exceeding 155 kcal/mol by integrating [CO] and [CO] groups into the BeF framework.
View Article and Find Full Text PDFNeuroendocrine prostate cancer drivers SOX2 and BRN2 confer differential responses to imipridones ONC201, ONC206, and ONC212 in prostate cancer cell lines.
Am J Transl Res
December 2024
Laboratory of Translational Oncology and Experimental Cancer Therapeutics, The Warren Alpert Medical School, Brown University Providence, RI 02903, USA.
Objectives: Prostate cancer (PCa) is a leading cause of cancer death in men worldwide. Approximately 30% of castrate-resistant PCa becomes refractory to therapy due to neuroendocrine differentiation (NED) that is present in <1% of de-novo tumors. First-in-class imipridone ONC201/TIC10 therapy has shown clinical activity against midline gliomas, neuroendocrine tumors, and PCa.
View Article and Find Full Text PDFThe Problem: People use social media platforms to chat, search, and share information, express their opinions, and connect with others. But these platforms also facilitate the posting of divisive, harmful, and hateful messages, targeting groups and individuals, based on their race, religion, gender, sexual orientation, or political views. Hate content is not only a problem on the Internet, but also on traditional media, especially in places where the Internet is not widely available or in rural areas.
View Article and Find Full Text PDFCyto-Genotoxic Assessment of Sulfoxaflor in Allium cepa Root Cells and DNA Docking Studies.
Microsc Res Tech
January 2025
Molecular Biology and Genetics Department, Faculty of Engineering and Natural Sciences, Uşak University, Uşak, Turkey.
Sulfoxaflor (SFX) is an insecticide that is commonly used for the control of sap-feeding insects. Since SFX is extensively applied globally, it has been implicated in the substantial induction of environmental toxicity. Therefore, in this study, Allium cepa roots have been employed to elucidate the potential cytogenotoxic effects of SFX in non-target cells by examination of mitotic index (MI), chromosomal aberrations (CAs), and DNA damage.
View Article and Find Full Text PDFPhysio-biochemical and molecular mechanisms of low nitrogen stress tolerance in peanut (Arachis hypogaea L.).
Plant Mol Biol
January 2025
Henan Key Laboratory for Molecular Ecology and Germplasm Innovation of Cotton and Wheat and Xinxiang Key Laboratory of Crop Root Biology and Green Efficient Production, School of Life Sciences, Henan Collaborative Innovation Center of Modern Biological Breeding, Henan Institute of Science and Technology, Xinxiang, 453003, Henan, China.
Nitrogen (N) is a major plant nutrient and its deficiency can arrest plant growth. However, how low-N stress impair plant growth and its related tolerance mechanisms in peanut seedlings has not yet been explored. To counteract this issue, a hydroponic study was conducted to explore low N stress (0.
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