Bidirectional transfer of phenyl and methyl groups between Pt(IV) and boron in platinum dipyridylborato complexes.

J Am Chem Soc

Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA.

Published: August 2008

In the presence of weakly Lewis basic DMSO methyl group migration between B and PtIV in dipyridylborato trihydrocarbyl PtIV complexes is reversible; the preferred direction of Ph group migration in THF solution is from PtIV to B.

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Source
http://dx.doi.org/10.1021/ja804222cDOI Listing

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