For Au-ceria catalysts prepared by deposition-precipitation method, the catalytic performance of water gas shift reaction was studied with different La loadings. In the complete doping range, ceria retains with its cubic fluorite structures. XRD, HRTEM and UV-Vis-DRS, studies showed that La doping can improve the activity of Au-ceria catalyst by stabilizing ceria and modifying its morphology. In addition, the test of catalyst stability evaluation also proved, that a better stability performance of Au-ceria catalyst can be realized by appropriate La doping. The Au/CL5.0 sample with 5 at % La doping showed the best performance in WGS reaction.
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ACS Nano
May 2022
Department of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Korea.
Acc Chem Res
July 2021
Eduard-Zintl-Institute of Inorganic and Physical Chemistry, Technical University of Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany.
ConspectusBecause ceria (CeO) is a key ingredient in the formulation of many catalysts, its catalytic roles have received a great amount of attention from experiment and theory. Its primary function is to enhance the oxidation activity of catalysts, which is largely governed by the low activation barrier for creating lattice O vacancies. Such an important characteristic of ceria has been exploited in CO oxidation, methane partial oxidation, volatile organic compound oxidation, and the water-gas shift (WGS) reaction and in the context of automotive applications.
View Article and Find Full Text PDFChemistry
August 2010
Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, 11510 Puerto Real, Cadiz, Spain.
The influence of the highly dispersed gold phase on the CO-support interaction occurring in two 2.5 wt % Au/Ce(0.62)Zr(0.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
April 2008
National Engineering Research Center of Chemical Fertilizer Catalyst at Fuzhou University, Fuzhou 350002, China.
For Au-ceria catalysts prepared by deposition-precipitation method, the catalytic performance of water gas shift reaction was studied with different La loadings. In the complete doping range, ceria retains with its cubic fluorite structures. XRD, HRTEM and UV-Vis-DRS, studies showed that La doping can improve the activity of Au-ceria catalyst by stabilizing ceria and modifying its morphology.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
March 2006
Department of Chemical and Biological Engineering, Tufts University, Medford, MA 02155, USA.
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