A discrete diffraction transform (DDT) is a novel discrete wavefield propagation model that is aliasing free for a pixelwise invariant object distribution. For this class of distribution, the model is precise and has no typical discretization effects because it corresponds to accurate calculation of the diffraction integral. A spatial light modulator (SLM) is a good example of a system where a pixelwise invariant distribution appears. Frequency domain regularized inverse algorithms are developed for reconstruction of the object wavefield distribution from the distribution given in the sensor plane. The efficiency of developed frequency domain algorithms is demonstrated by simulation.
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http://dx.doi.org/10.1364/ao.47.003481 | DOI Listing |
J Am Chem Soc
January 2025
Department of Chemistry, 1102 Natural Sciences II, University of California, Irvine, California 92697, United States.
The development of molecular species with switchable magnetic properties has been a long-standing challenge in chemistry. One approach involves binding an analyte, such as protons, to a compound to trigger a change in magnetism. Transition metal complexes have been targeted for this type of magnetic modulation because they can undergo changes in their spin states.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.
Understanding the impact of oxidative modification on protein structure and functions is essential for developing therapeutic strategies to combat macromolecular damage and cell death. However, selectively inducing oxidative modifications in proteins under physiological conditions remains challenging. Herein we demonstrate that [VO{(OCH)CCHOH}] (V-OH) hybrid metal-oxo cluster can be used for selective protein oxidative cleavage and modifications.
View Article and Find Full Text PDFInorg Chem
January 2025
Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India.
Metal complexes with tunable ligands play a crucial role in olefin polymerization and impart control over molecular weight, crystallinity, and stereoregularity. We report the single-step synthesis of imine-phenoxy ligands in excellent yields (81-93%). The identity of electronically tuned imine-phenoxy ligands was unambiguously ascertained by using a combination of spectroscopic and analytical methods.
View Article and Find Full Text PDFMolecules
November 2024
Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102A, HR-10000 Zagreb, Croatia.
In this study, we report the syntheses, crystal structures and magnetic properties of ternary copper(II) coordination compounds with l-homoserine (l-Hhser) and 1,10-phenanthroline (phen). Six new coordination compounds were obtained: [Cu(l-hser)(HO)(phen)]SO·5HO (), [Cu(μ-l-hser)(HO)(phen)][Cu(l-hser)(HO)(phen)](SO)∙12HO (), {[Cu(μ-l-hser)(HO)(phen)][Cu(μ-l-hser)(phen)]SO·6HO} (), {[Cu(μ-l-hser)(HO)(phen)]SO·3HO} (), [Cu(l-hser)(HO)(phen)][Cu(l-hser)(CHOH)(phen)]SO·4HO () and {[Cu(l-hser)(CHOH)(phen)][Cu(μ-l-hser)(phen)]SO·5CHOH} () It was shown that slight differences in water content in the synthetic mixtures highly influence the final product, so in some cases, two or three different products were obtained. The compounds were characterized by single-crystal X-ray diffraction and ESR spectroscopy.
View Article and Find Full Text PDFBiomed Opt Express
December 2024
Department of Ophthalmology, Stanford University, Palo Alto, CA 94303, USA.
We explore camera-based pupil tracking using high-level programming in computing platforms with end-user discrete and integrated central processing units (CPUs) and graphics processing units (GPUs), seeking low calculation latencies previously achieved with specialized hardware and programming (Kowalski et al., [Biomed. Opt.
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