Palladium-catalyzed hydrophosphorylation and hydrophosphinylation of cyclopropenes.

Org Lett

Department of Chemistry, Univeristy of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-75832, USA.

Published: August 2008

Novel transition-metal-catalyzed addition of P-H entities across the cyclopropene double bond has been developed. This transformation allows for mild and efficient preparation of phosphorus-containing cyclopropanes in good yields and high degrees of diastereoselectivity.

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Source
http://dx.doi.org/10.1021/ol8011138DOI Listing

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