Combining triflic acid-promoted glycosylations of trichloroacetimidates with reductive opening of benzylidene acetals with triflic acid and triethylsilane as one-pot procedures provides access to a wide range of disaccharides and 2,4- and 3,4-branched trisaccharides.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2814312PMC
http://dx.doi.org/10.1021/ol801076wDOI Listing

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