This work shows the applicability of two-dimensional (2D) (1)H-(13)C heteronuclear correlation (HETCOR) nuclear magnetic resonance (NMR) spectroscopy to the characterization of whole soils. A combination of different mixing times and cross polarization (CP) methods, namely Lee-Goldberg (LG)-CP and Ramp-CP are shown to afford, for the first time, intra- and inter- molecular connectivities, allowing for molecular assemblage information to be obtained on a whole soil. Our results show that, for the brackish marsh histosol under study, two isolated domains could be detected. The first domain consists of O-alkyl and aromatic moieties (lignocellulose material), while the second domain is comprised of alkyl type moieties (cuticular material). The role of these domains is discussed in terms of hydrophobic organic compound sorption within soil organic matter (SOM), including the possible effects of wetting and drying cycles.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.2134/jeq2007.0137 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Sponge exhalent metabolites influence coral reef picoplankton dynamics.
Sci Rep
December 2024
Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Falmouth, USA.
Coral reef sponges efficiently take up particulate and dissolved organic matter (DOM) from the water column and release compounds such as nucleosides, amino acids, and other dissolved metabolites to the surrounding reef via their exhalent seawater, but the influence of this process on reef picoplankton and nutrient processing is relatively unexplored. Here we examined the impact of sponge exhalent on the reef picoplankon community and subsequent alterations to the reef dissolved metabolite pool. We exposed reef picoplankton communities to a sponge exhalent water mixture (Niphates digitalis and Xestospongia muta) or filtered reef seawater (control) in closed, container-based dark incubations.
View Article and Find Full Text PDFVegetation restoration can be effective in containing gully head advance. However, the effect of vegetation restoration type on soil aggregate stability and erosion resistance at the head of the gully is unclear. In this study, five types of vegetation restoration-Pinus tabulaeformis (PT), Prunus sibirica (PS), Caragana korshinskii (CKS), Hippophae rhamnoides (HR), and natural grassland (NG, the dominant species is Leymus chinensis)-in the gully head were studied.
View Article and Find Full Text PDFVersatile g-CN/AlOOH Nanocomposites: Efficient photocatalyst for Dye Removal, Algae Inactivation, and Glucose Detection.
Chemosphere
December 2024
Department of Chemical and Materials Engineering, National University of Kaohsiung, Kaohsiung 81148, Taiwan. Electronic address:
Visible light photocatalysts hold great promise for water purification, yet research on highly efficient, non-toxic photocatalysts is limited. This study synthesized novel g-CN/AlOOH photocatalytic nanocomposites via thermal condensation, enhancing adsorption and visible light degradation by 36-fold and 11-fold, respectively, compared to g-CN alone. The nanocomposites achieved a 98% removal rate of methyl orange under xenon lamp irradiation (>400 nm) for 1 hour.
View Article and Find Full Text PDFEnhanced coagulation of Microcystis aeruginosa using titanium xerogel coagulant.
Chemosphere
December 2024
Key Laboratory of Health Intelligent Perception and Ecological Restoration of River and Lake, Ministry of Education, Hubei University of Technology, Wuhan 430068, China; Innovation Demonstration Base of Ecological Environment Geotechnical and Ecological Restoration of Rivers and Lakes, School of Civil and Environmental Engineering, Hubei University of Technology, Wuhan 430068, China. Electronic address:
Cyanobacterial blooms are prevalent globally and present a significant threat to water security. Titanium salt coagulants have garnered considerable attention due to their superior coagulation properties and the absence of metal residue risks. This paper explored the influencing factors in the coagulation process of titanium xerogel coagulant (TXC), the alterations in cell activity during floc storage, and the release of cyanobacterial organic matters, thereby determining the application scope of TXC for cyanobacterial water treatment.
View Article and Find Full Text PDFThe role of biodegradable plastics in lignite anaerobic digestion: Changes of organics transformation and metabolic pathway.
Bioresour Technol
December 2024
School of Energy Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China. Electronic address:
Biodegradable plastics (BPs) and lignite, both rich in organic matter, present significant challenges for efficient conversion into clean energy. This study examined the anaerobic co-digestion of BPs and lignite under controlled laboratory conditions. The results demonstrated that the co-digestion of polylactic acid (PLA) and lignite (at a 1:2 mass ratio, with 5 g PLA and 10 g lignite as the model system) rapidly acclimated to the anaerobic environment, enhancing cumulative biogas production by 57 % compared to the mono-digestion of lignite alone.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!