Transmission X-ray mirrors have been fabricated from 300-400 nm-thick low-stress silicon nitride windows of size 0.6 mm x 85 mm. The windows act as a high-pass energy filter at grazing incidence in an X-ray beam for the beam transmitted through the window. The energy cut-off can be selected by adjusting the incidence angle of the transmission mirror, because the energy cut-off is a function of the angle of the window with respect to the beam. With the transmission mirror at the target angle of 0.22 degrees , a 0.3 mm x 0.3 mm X-ray beam was allowed to pass through the mirror with a cut-off energy of 10 keV at the Cornell High Energy Synchrotron Source. The energy cut-off can be adjusted from 8 to 12 keV at an angle of 0.26 degrees to 0.18 degrees , respectively. The observed mirror transmittance was above 80% for a 300 nm-thick film.
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http://dx.doi.org/10.1107/S0909049508007607 | DOI Listing |
Chem Commun (Camb)
January 2025
Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge CB21EW, UK.
Metal-air batteries are promising energy storage systems with high specific energy density and low dependence on critical materials. However, their development is hindered by slow kinetics, low roundtrip efficiency, deficient capacity recovery, and limited lifetime. This work explores the effect of cycling protocols on the lifetime of Li-O cells, and the interplay between electrolyte composition and the upper cut-off voltage during charge.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Department of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu, 30010, Taiwan.
A highly electron-rich S,N heteroacene building block is developed and condensed with FIC and Cl-IC acceptors to furnish CT-F and CT-Cl, which exhibit near-infrared (NIR) absorption beyond 1000 nm. The C-shaped CT-F and CT-Cl self-assemble into a highly ordered 3D intermolecular packing network via multiple π-π interactions in the single crystal structures. The CT-F-based organic photovoltaic (OPV) achieved an impressive efficiency of 14.
View Article and Find Full Text PDFNutrients
December 2024
Department of Emergency and Post-Emergency Psychiatry, CHU Montpellier, INSERM, University of Montpellier, 34295 Montpellier, France.
Objective: Developing a scoring assessment tools for the determination of low bone mass for age at lumbar spine and hip in patients with anorexia nervosa (AN).
Methods: The areal bone mineral density (aBMD) was determined with dual-energy X-ray absorptiometry (DXA). In 331 women with AN and 121 controls, aged from 14.
Luminescence
January 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, China.
Hypochlorous acid (HClO) is released by immune cells in the immune system, and it helps the body fight off infections and inflammation by killing bacteria, viruses, and other pathogens. However, tissue damage or apoptosis may also be induced by excess HClO. On this basis, we designed the probe TPE-NS by choosing tetraphenylethylene (TPE) as the luminescent unit and dimethylthiocarbamoyl chloride as the recognition site.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
College of Energy, Xiamen University, 361005, Xiamen, China.
Pushing the limit of the charging cut-off voltage inevitably leads to the instability of bulk and interfacial structures. Herein, one-step dual-modified LiCoO (LCO) is achieved by thermodynamic decomposition of lithiuim salts on the surface, featuring F-doped bulk and LiF & LiBO coating layers. Notably, such artificial near-surface reconfiguration effectively suppresses Co dissolution, structural deconstruction and electrolyte side reactions during repeated lithiation/delithiation processes.
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