This paper reports four homochiral zinc phosphonates, alpha-(S)-[Zn 2(pemp)(pempH)Cl] (1), alpha-(R)-[Zn 2(pemp)(pempH)Cl] (2), beta-(S)-[Zn 2(pemp)(pempH)Cl] (3), and beta-(R)-[Zn 2(pemp)(pempH)Cl] (4) [pempH 2 = (1-phenylethyl)amino]methylphosphonic acid]. Both 1 and 2 are enantiomers, crystallizing in an orthorhombic P2(1)2(1)2(1) space group, while 3 and 4 are polymorphic phases of 1 and 2, respectively, crystallizing in a monoclinic P2(1) space group. The polymorphism is induced by temperature or additional organic molecules.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ic800663t | DOI Listing |
Publication Analysis
Top Keywords
homochiral zinc
8
zinc phosphonates
8
space group
8
polymorphism homochiral
4
phosphonates paper
4
paper reports
4
reports homochiral
4
phosphonates alpha-s-[zn
4
2pemppemphcl]
4
alpha-s-[zn 2pemppemphcl]
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!