In this paper, swabbings from various public areas in 28 different cities throughout the United States were collected. A wide variety of objects were tested, ranging from park benches and telephones to sign posts and mailboxes. Inorganic anions and cations common in low explosives were detected simultaneously using capillary zone electrophoresis. Organic high explosives including nitroaromatics, nitramines, and nitrate esters were detected using gas chromatography with a pulsed-discharge electron capture detector. Confirmation of selected results was performed by ion chromatography and negative ion chemical ionization GC/MS. In general the results provide two major conclusions: (i) with the exception of nitrate, most low explosive oxidizers are rare in the environment; (ii) no organic explosives or significant interferences to these explosives were detected.
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http://dx.doi.org/10.1111/j.1556-4029.2008.00743.x | DOI Listing |
Sensors (Basel)
January 2025
Laboratory of Sensors/Actuators and Energy Harvesting, National Institute for Research and Development in Electrical Engineering ICPE-CA, 030138 Bucharest, Romania.
The use of hydrogen as fuel presents many safety challenges due to its flammability and explosive nature, combined with its lack of color, taste, and odor. The purpose of this paper is to present an electrochemical sensor that can achieve rapid and accurate detection of hydrogen leakage. This paper presents both the component elements of the sensor, like sensing material, sensing element, and signal conditioning, as well as the electronic protection and signaling module of the critical concentrations of H.
View Article and Find Full Text PDFSensors (Basel)
January 2025
Department of Information Technology, Quaid e Awam University, Nawabshah 67450, Pakistan.
Detection of anomalies in video surveillance plays a key role in ensuring the safety and security of public spaces. The number of surveillance cameras is growing, making it harder to monitor them manually. So, automated systems are needed.
View Article and Find Full Text PDFMolecules
January 2025
Department of Law, University of Bergamo, Via Moroni 255, 24127 Bergamo, Italy.
Background: The detection of explosives in crime scene investigations is critical for forensic science. This study explores the application of laser desorption (LD) ion mobility spectrometry (IMS) as a novel method for this purpose utilising a new IMS prototype developed by MaSaTECH.
Methods: The LD sampling technique employs a laser diode module to vaporise explosive traces on surfaces, allowing immediate analysis by IMS without sample preparation.
Anal Chem
January 2025
Los Alamos National Laboratory, Q-5, High Explosives Science and Technology, Los Alamos, New Mexico 87545, United States.
Alteration analysis (ALA), an unsupervised chemometric technique, was evaluated for its ability to discover statistically significant trends in chromatographic data sets. Recently introduced, adoption of ALA has been limited due to uncertainty regarding its sensitivity to minor changes, and there are no rules implementing ALA especially for multivariate data sets such as liquid or gas chromatography coupled to mass spectrometry. Using in-silico data sets, ALA limits of discovery for various signal-to-noises (S/Ns), rates of change across samples, and a number of samples were assessed.
View Article and Find Full Text PDFCrit Rev Anal Chem
January 2025
SIMETRI, Inc, Winter Park, Florida, USA.
This review highlights recent advancements and challenges in fluorescence-based chemical sensors for selective and sensitive detection of perchlorate, a persistent environmental pollutant and global concern due to its health and safety implications. Perchlorate is a highly persistent inorganic pollutant found in drinking water, soil, and air, with known endocrine-disruptive properties due to its interference with iodide uptake by the thyroid gland. Human exposure mainly occurs through contaminated water and food.
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