Novel cross-linked sulfonated poly(ether sulfone)s, prepared by azide-assisted thermal irradiation, show not only low methanol permeability but also exceptionally high proton conductivity with oxidative and hydrolytic stability.
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College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, P.R. China.
Valvular heart disease (VHD) poses a significant threat to human health, and the transcatheter heart valve replacement (THVR) is the best treatment for severe VHD. Currently, the glutaraldehyde cross-linked commercial bioprosthetic heart valves (BHVs) remain the first choice for THVR. However, the cross-linking by glutaraldehyde exhibits several drawbacks, including calcification, inflammatory reactions, and difficult endothelialization, which limits the longevity and applicability of BHVs.
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College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei, China. Electronic address:
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Article Synopsis
- A new synthetic hydrogel was developed by cross-linking poly(vinylphosphonates) using controlled polymerization methods and photoinitiated thiol-ene click chemistry, allowing for precise adjustments in composition and properties.
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