New catalytic route to borasiloxanes.

Chem Commun (Camb)

Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland.

Published: June 2008

A new, highly selective method for effective synthesis of boryl silyl ethers (borasiloxanes) via O-borylation of silanols with vinylboronates catalyzed by the Ru-H complexes [RuHCl(CO)(PCy3)2] and [RuHCl(CO)(PPh3)3] is described.

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Source
http://dx.doi.org/10.1039/b801013gDOI Listing

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