In a bioinspired methodology, positively charged polypeptides and polyamines directly catalyse ZnO mineralization under "green" conditions of room temperature and neutral pH. The polyamines not only act as mineralizing agents for the formation of ZnO nanoparticles, but also self-assemble the nanoparticles to form spindle-like morphologies at these very ambient conditions. Both the directional growth of ZnO and its luminescent property have a pH dependency. At higher pH, the ZnO shape changes to a rodlike morphology that exhibits green photoluminescence with different intensity than that for ZnO spindles.
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http://dx.doi.org/10.1002/chem.200800129 | DOI Listing |
J Int Soc Prev Community Dent
December 2024
College of Dentistry, Mosul University, Mosul, Iraq.
Background And Aim: In dental clinics, disinfecting alginate impression materials is a critical practice to prevent cross-infection. Recently, zinc oxide nanoparticles (ZnO NPs) have been explored for their potential antimicrobial properties, making them promising additives for dental materials. This study investigates the antimicrobial activity of ZnO NPs incorporated into alginate impression materials and assesses the impact on material flow.
View Article and Find Full Text PDFAnim Reprod
January 2025
Hebei Key Laboratory of Animal Diversity, College of Life Sciences, Langfang Normal University, Hebei Langfang, China.
More than 90% of spermatozoa of boars in pork producing countries is stored in liquid at 17 °C; however, the quality of these spermatozoa is affected by bacterial breeding and oxidative damage. This study analyzed sperm quality and sperm capacitation after storage to study the effects of the effects of ZnO nanoparticles (ZnO NPs) supplementation on seminal plasma (SP)-free sperm preservation. We investigated the effects of adding 20, 50, 100 and 200 μg/mL of ZnO NPs to a seminal free boar sperm diluent over a 7-day period at 17 °C to assess the changes in non-capacitated/capacitated sperm quality parameters, antioxidant capacity, ATP content and extent of protein tyrosine phosphorylation.
View Article and Find Full Text PDFNanoscale Adv
January 2025
Department of Materials Science, University of Milano-Bicocca Via Cozzi 55 Milano I-20125 Italy
Hybrid nanoscintillators, which feature a heavy inorganic nanoparticle conjugated with an organic emitter, represent a promising avenue for advancements in diverse fields, including high-energy physics, homeland security, and biomedicine. Many research studies have shown the suitability of hybrid nanoscintillators for radiation oncology, showing potential to improve therapeutic results compared to traditional protocols. In this work, we studied SiO/ZnO nanoparticles functionalized with porphyrin as a photosensitizer, capable of producing cancer cytotoxic reactive oxygen species for possible use in radio-oncological therapeutics.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Karlsruhe Institute of Technology KIT, Institute for Chemical Technology and Polymer Chemistry, Kaiserstr. 12, Fakultät für Chemie, 76131, Karlsruhe, GERMANY.
In the frame of developing a sustainable chemical industry, heterogeneously catalyzed CO2 hydrogenation to methanol has attracted considerable interest. However, the Cu-Zn based catalyst system employed in this process is very dynamic, especially in the presence of the products methanol and water. Deactivation needs to be prevented, but its origin and mechanism are hardly investigated at high conversion where product condensation is possible.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Laboratory of Atomic-scale and Micro & Nano Manufacturing, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.
Different application domains impose diverse and often conflicting requirements on the optoelectronic performance of metal oxide semiconductor (MOS) thin-film transistors (TFTs). These varying demands present substantial challenges in the selection of TFT materials and the optimization of device performance. This study begins by examining three primary application areas for TFTs: display drivers, photodetectors, and optoelectronic synapses.
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