A simple and efficient synthesis of N-sulfonyl ketimines through a Pd-catalyzed cross-coupling reaction between organoboronic acids and tosylbenzimidoyl chlorides under mild conditions has been developed.
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http://dx.doi.org/10.1039/b802867b | DOI Listing |
Environ Technol
January 2025
Tekirdağ Metropolitan Municipality, TESKİ, Water and Sewerage Administration, Tekirdağ, Turkey.
This study explores variations in groundwater (GW) pH, conductivity, ammonium, iron, and manganese parameters to reveal prospective interactions having an impact on the dissolved metal concentrations. To this end, bivariate and partial correlation procedures were applied to the data to obtain incisive evaluation. Besides characterisation efforts, photocatalytic iron and manganese removal experiments were also carried out with Ni-doped TiO nano-composite thin films (TFs) on real GW samples.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Applied Physics and Integrated Education Institute for Frontier Science and Technology (BK21 Four), Kyung Hee University, Yongin 17104, Korea.
One-dimensional (1D) vertical nitrides are highly attractive for light-emitting diode (LED) applications because they are useful for overcoming the drawbacks of conventional GaN planar structures. However, the internal quantum efficiency (IQE) of GaN multi-quantum-well (MQW) nanowire (NW) LEDs, typical 1D GaN structures, is still too low to replace standard planar LEDs. Here, we report a phenomenon of light amplification from core-shell InGaN/GaN NW LEDs by incorporating graphene quantum dots (GQDs).
View Article and Find Full Text PDFLangmuir
January 2025
Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe, Mizuho, Nagoya 467-8603, Aichi, Japan.
In this study, we demonstrate a novel and efficient fabrication methodology for nonclose-packed, two-dimensional (2D) colloidal crystals exhibiting square lattice structures. In our recent work, we detailed the formation of 2D colloidal crystals via the electrostatic adsorption of three-dimensional (3D) charged colloidal crystals onto oppositely charged substrates. These 3D colloidal crystals possessed a face-centered cubic (FCC) lattice structure with their (111) planes aligned parallel to the substrate, facilitating the formation of 2D crystals with triangular lattice arrangements upon adsorption.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, P. R. China.
Membranes have extensive applications in catalysis, separation, antimicrobial activities, and sensing. However, developing a simple and environmentally friendly method for preparing membranes remains challenging. Here, we report a novel strategy for fabricating self-standing inorganic-organic composite films at the miscible liquid/liquid interface using a soft spray technique.
View Article and Find Full Text PDFPediatr Surg Int
January 2025
Department of Paediatric Surgery, Children's Health Ireland at Crumlin, Dublin, Ireland.
Background: Appendicectomy is a common procedure in children. Regional anaesthesia helps reduce requirements for opioids and hospital stay and enhances recovery. Laparoscopic-assisted Transversus Abdominus Plane block (L-TAP) was shown to be efficient and potentially superior to port site infiltration (PSI); however, this was not previously studied in paediatric appendicitis.
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