Distant dipolar fields among nuclear spins on macroscopic scales in the gas phase are reported for the first time. Their observation via interatomic multiple quantum coherences requires high nuclear spin polarization corresponding to spin temperatures of a few mK, which is generated in laser-polarized 3He, and proper control of the gas diffusion through a heavier buffer gas. This combination of physics at low and ambient temperatures opens up new ways of studying the relative translational diffusion of atoms and of gas diffusion in structures with a large range of length scales.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevLett.100.213001DOI Listing

Publication Analysis

Top Keywords

distant dipolar
8
dipolar fields
8
macroscopic scales
8
gas diffusion
8
fields laser-polarized
4
laser-polarized gases
4
gases macroscopic
4
scales distant
4
fields nuclear
4
nuclear spins
4

Similar Publications

Theoretical and simulated analyses of selective homonuclear dipolar recoupling sequences serve as primary tools for understanding and determining the robustness of these sequences under various conditions. In this article, we investigate the recently proposed first-order dipolar recoupling sequence known as MODIST (Modest Offset Difference Internuclear Selective Transfer). We evaluate the MODIST transfer efficiency, assessing its dependence on rf-field strengths and the number of simulated spins, extending up to 10 spins.

View Article and Find Full Text PDF

Robust parahydrogen-induced polarization at high concentrations.

Sci Adv

July 2024

Institut für Theoretische Physik and IQST, Albert-Einstein Allee 11, Universität Ulm, 89081 Ulm, Germany.

Parahydrogen-induced polarization (PHIP) is a potent technique for generating target molecules with high nuclear spin polarization. The PHIP process involves a chemical reaction between parahydrogen and a target molecule, followed by the transformation of nuclear singlet spin order into magnetization of a designated target nucleus through magnetic field manipulations. Although the singlet-to-magnetization polarization transfer process works effectively at moderate concentrations, it is observed to become much less efficient at high molar polarization, defined as the product of polarization and concentration.

View Article and Find Full Text PDF

Pulse electron double resonance (PELDOR), also called double electron-electron resonance (DEER), is a technique capable of measuring the strength of electron spin dipolar interactions, revealing spin-spin distance distributions in ordered and disordered solid materials. Previous work has shown that PELDOR signals acquire an out-of-phase component under conditions of high electron spin polarization, such as at low temperatures and high fields. In this paper, we show theoretically and experimentally that the size and sign of this effect depends on the macroscopic shape of the sample and its orientation in the external magnetic field.

View Article and Find Full Text PDF

Dipolar field effects in a solid-state NMR maser pumped by dynamic nuclear polarization.

Phys Chem Chem Phys

April 2023

Laboratoire des Biomolécules, LBM, Département de Chimie, Ecole Normale Supérieure, PSL University, Sorbonne Université, CNRS, 75005 Paris, France.

We report the observations and the analysis of a pulsed solid state sustained maser generated by proton spins hyperpolarized by Dynamic Nuclear Polarization (DNP) at cryogenic temperatures. Similar unconventional behaviour was observed recently [Weber , , 2019, , 21278-21286], with induction decays exhibiting multiple asymmetric maser pulses for short time (100 ms) and persistent for tens of second, when the spins are polarized negatively. We present new evidence of such DNP NMR masers, and shed light on previously observed but unexplained features of these masers through simulations of the non-linear spin dynamics using the Bloch-Maxwell-Provotrov (BMP) equations for radiation damping and DNP, and taking into account the (distant) dipolar field.

View Article and Find Full Text PDF

Nonlocal Detection of Interlayer Three-Magnon Coupling.

Phys Rev Lett

January 2023

Fert Beijing Institute, MIIT Key Laboratory of Spintronics, School of Integrated Circuit Science and Engineering, Beihang University, Beijing 100191, China.

A leading nonlinear effect in magnonics is the interaction that splits a high-frequency magnon into two low-frequency magnons with conserved linear momentum. Here, we report experimental observation of nonlocal three-magnon scattering between spatially separated magnetic systems, viz. a CoFeB nanowire and a yttrium iron garnet (YIG) thin film.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!