We present an optical signature of a hybridization between a localized quantum dot state and a filled continuum. Radiative recombination of the negatively charged trion in a single quantum dot leaves behind a single electron. We show that in two regions of vertical electric field, the electron hybridizes with a continuum through a tunneling interaction. The hybridization manifests itself through an unusual voltage dependence of the emission energy and a non-Lorentzian line shape, features which we reproduce with a theory based on the Anderson Hamiltonian.
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http://dx.doi.org/10.1103/PhysRevLett.100.176801 | DOI Listing |
Nanoscale
January 2025
Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, CA 94550, USA.
Quantum dots (QDs) are promising materials for optoelectronic applications, but their widespread adoption requires controllable, selective, and scalable deposition methods. While traditional methods like spin coating and drop casting are suitable for small-scale deposition onto flat substrates, and ink-jet printing offers precision for small areas, these methods struggle with conformal deposition onto non-planar, large area substrates or selective deposition onto large area chips. Electrophoretic deposition (EPD) is an efficient and versatile technique capable of achieving conformal and selective area deposition over large areas, but its application to QD films has been limited.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Computer Engineering, Faculty of Engineering, Bu-Ali Sina University, Hamedan, Iran.
According to recent research, with the ever-increasing use of Internet of Things (IoT) devices, there has arisen an ever-growing need for high-performance yet low-power circuits that can efficiently process information. Quantum-dot Cellular Automata (QCA) has emerged as a promising alternative to conventional complementary metal-oxide-semiconductor (CMOS) technology due to its great potential in digital design at nanoscale levels on account of very low power consumption and very high processing speed. However, QCA circuits are inherently prone to faults due to variations in manufacturing processes and due to the influence of environmental factors.
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January 2025
Department of Physics, College of Science, University of Thi-Qar, Nasiriya, Iraq.
This work studies the generation of the orbital angular momentum (OAM) beam in the double quantum dot-metal nanoparticle (DQD-MNP) system under the application of the OAM beam. First, an analytical model is derived to attain the relations of probe and generated fields as a distance function in the DQD-MNP system under OAM applied field and spontaneously generated coherence (SGC) components. The calculation here is of material property; it differs from others by calculating energy states of the DQDs and the computation of the transition momenta between quantum dot (QD)-QD and QD-wetting layer (WL) transitions.
View Article and Find Full Text PDFBiosens Bioelectron
January 2025
Key Lab for Special Functional Materials of Ministry of Education, and School of Nanoscience and Materials Engineering, Henan University, 475004, Kaifeng, China. Electronic address:
Influenza A virus (IAV) and influenza B virus (IBV) with similar symptoms of infection caused a serious disease burden and economic losses in annual epidemic season, so it is important to quickly and accurately detect and distinguish between IAV and IBV during influenza season. Herein, the quantum dot microspheres (QDMS) were synthesized and applied to lateral flow immunoassays (LFIA), and a point-of-care (POC) biosensor that can discriminately and simultaneously diagnose IAV and IBV within 10 min was established. A double-sandwich QDMS nanotags was synthesized by immobilizing hydrophobic quantum dots (QDs) with chemical bonding method on a silica sphere template with an outer silica shell protection showed excellent stability and high fluorescence.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Ritsumeikan University: Ritsumeikan Daigaku, Applied Chemistry, B805 Biolink, 1-1-1 Nojihigashi, 525-8577, Kusatsu, JAPAN.
Inorganic photochromic materials offer several advantages over organic compounds, including relatively inexpensive and higher thermal stability. However, tuning their color with the same component has remained a significant challenge. In this study, we demonstrate that the photochromic color of Cu-doped ZnS nanocrystals (NCs), which is initially pale yellow before light irradiation, can be tuned from gray to brown by adjusting the surface stoichiometry of Zn and S, which is controlled through the use of thiol and non-thiol ligands.
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