Organically templated metal-organic framework with 2-fold interpenetrated {3(3).5(9).6(3)}-lcy net.

Chem Commun (Camb)

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.

Published: June 2008

A new organic cation templated Zn(II) complex (Et3NH)[Zn4(ip)3(bta)3] (, ip = isophthalate, Hbta = benzotriazole) which consists of plate-like Zn4(bta)3 units bridged by ip ligands is reported; it is the first example of a 6-connected uninodal {3(3).5(9).6(3)}-lcy net which has never been observed previously in MOFs but has been theoretically anticipated.

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http://dx.doi.org/10.1039/b800017dDOI Listing

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