A new organic cation templated Zn(II) complex (Et3NH)[Zn4(ip)3(bta)3] (, ip = isophthalate, Hbta = benzotriazole) which consists of plate-like Zn4(bta)3 units bridged by ip ligands is reported; it is the first example of a 6-connected uninodal {3(3).5(9).6(3)}-lcy net which has never been observed previously in MOFs but has been theoretically anticipated.
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http://dx.doi.org/10.1039/b800017d | DOI Listing |
Chemistry
May 2009
Department of Chemistry, Zhengzhou University, Henan, China.
Unusual {3(3)5(9)6(3)}-lcy topology has been found in an uncommon 3D six-connected, two-fold interpenetrated {3(3)5(9)6(3)}-lcy net (illustrated). The coordinated SO(4) (2-) anions in this framework can undergo a full exchange with Cl(-) anions, in the course of which the crystals change color as shown. The process has a solvent-mediated rather than a solid-state mechanism.
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