Silaboration of 1,3-enynes catalyzed by group 10 metal complexes affords 1,3-dienes with vinylborane and vinylsilane functions or 1,2-dienes with allylborane and vinylsilane functions. The type of product formed is determined by the size of the alkyne substituent.
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| http://dx.doi.org/10.1021/ol800768x | DOI Listing |
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