LaF(3) thin films of different thicknesses were deposited on CaF(2) (111) and silicon substrates at a relatively low substrate temperature of 150 degrees C. Optical (transmittance, reflectance, refractive index, and extinction coefficient) and mechanical (morphology and crystalline structure) properties have been investigated and are discussed. It is shown that LaF(3) thin films deposited on CaF(2) (111) substrates are monocrystalline and have a bulklike dense structure. Furthermore, it is presented that low-loss LaF(3) thin films can be deposited not only by boat evaporation but also by electron beam evaporation.
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http://dx.doi.org/10.1364/ao.47.00c157 | DOI Listing |
LaAlF nanocomposite coatings with various amounts of AlF in LaF were deposited on the fused silica substrate using double-source electron beam co-evaporation. The effects of the material composition on the chemical composition, optical properties, microstructure properties, and residual stress of these deposited coatings were investigated. The results showed that although the doping of AlF led to a reduction in the refractive index, the overall performance of the nanocomposites showed remarkable improvement.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2024
Graduate School of Engineering, Kyoto University, Nishikyo, Kyoto 615-8510, Japan.
All-solid-state fluoride batteries have the potential to achieve energy densities significantly higher than those of lithium-ion batteries. A common cathode material for fluoride batteries is Cu. Cu has a low polarization, but its rapid capacity degradation due to grain growth and subsequent delamination from the solid-state electrolyte are critical issues.
View Article and Find Full Text PDFSmall
October 2023
Thin Film Materials Research Center, Korea Research Institute of Chemical Technology, Daejeon, 34114, Republic of Korea.
The precisely tailored refractive index of optical materials is the key to utilizing and manipulating light during its propagation through the matrix, thereby improving their application performances. In this paper, mesoporous metal fluoride films with engineered composition (MgF :LaF ) are demonstrated to achieve finely tunable refractive indices. These films are prepared using a precursor-derived one-step assembly approach via the simple mixing of precursor solutions (Mg(CF OO) and La(CF OO) ); then pores are formed simultaneously during solidification owing to the inherent instability of La(CF OO) .
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2021
Graduate School of Human and Environmental Studies, Kyoto University, Yoshida Nihonmatsu Cho, Sakyo, Kyoto 606-8501, Japan.
Developing high-performance solid electrolytes that are operable at room temperature is one of the toughest challenges related to all-solid-state fluoride-ion batteries (FIBs). In this study, tetragonal β-PbSnF, a promising solid electrolyte material for mild-temperature applications, was modified through annealing under various atmospheres using thin-film models. The annealed samples exhibited preferential growth and enhanced ionic conductivities.
View Article and Find Full Text PDFActa Biomater
November 2020
Department of Oncology, University of Alberta, 11560 University Avenue NW, Edmonton, AB T6G 1Z2, Canada; Department of Surgery, University of Alberta, 8440 - 112 Street NW, Edmonton, AB T6G 2B7, Canada.
Photodynamic Therapy (PDT) is an effective treatment modality for cancers, with Protoporphyrin IX (PPIX)-based PDT being the most widely used to treat cancers in patients. However, PDT is limited to superficial, thin (few mm in depth) lesions that can be accessed by visible wavelength light. Interstitial light-delivery strategies have been developed to treat deep-seated lesions (i.
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