Measuring chirality in NMR in the presence of a static electric field.

J Chem Phys

Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.

Published: April 2008

The scalar Hamiltonian of nuclear spins in the presence of a static electric field supports chirality. However, the eigenvalues of the Hamiltonian are not chiral; hence, chirality is not manifested in the usual NMR experiment. In this work, we show that the magnetization response to certain radio frequency pulse sequences exhibits chirality as well as handedness.

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http://dx.doi.org/10.1063/1.2888555DOI Listing

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