Ligands that enforce unnatural stereospinomers.

Dalton Trans

Inorganic Chemistry Laboratory, Department of Chemistry, University of Athens, GR-15771, Athens, Greece.

Published: May 2008

AI Article Synopsis

  • The study presents computational findings that reveal new combinations of stereoisomers and spin states in d(4) and d(8) metal complexes.
  • These combinations were not observed before and were achieved through the use of encapsulating ligands.
  • The encapsulating ligands force a tetrahedral coordination geometry in these complexes, leading to these novel results.

Article Abstract

Computational evidence is provided for the existence of combinations of a stereoisomer and a spin state not previously observed in d(4) and d(8) complexes, achieved by means of encapsulating ligands that enforce a tetrahedral coordination.

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Source
http://dx.doi.org/10.1039/b802462fDOI Listing

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