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Intermolecular radical addition reactions of alpha-iodo cycloalkenones and a synthetic study of the formal synthesis of enantiopure fawcettimine. | LitMetric
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Intermolecular radical addition reactions of alpha-iodo cycloalkenones and a synthetic study of the formal synthesis of enantiopure fawcettimine.

Kuan-Miao Liu Chi-Min Chau Chin-Kang Sha

Chem Commun (Camb)

School of Applied Chemistry, Chung Shan Medical University, Taichung 402, Taiwan, ROC.

Published: January 2008

The generation of alpha-carbonyl vinyl radicals from alpha-iodo cycloalkenones, the scope of their participation in intermolecular addition reactions with electron-withdrawing olefins are studied and a synthetic study of the formal synthesis of enantiopure fawcettimine using this reaction is described.

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http://dx.doi.org/10.1039/b714078aDOI Listing

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