AI Article Synopsis

  • Phosphorus removal from wastewater is crucial, and this study investigates using ferric chloride and tannic acid (TA) as a coagulant and aid respectively for effective coagulation.
  • TA was found to enhance settling speed by forming larger flocs, reduce residual iron that causes discoloration, and slightly improve phosphorus removal efficiency.
  • The precipitate created through TA-aided coagulation releases phosphorus more rapidly than traditional ferric phosphate, suggesting its potential use as a slow-release fertilizer, with analytical techniques confirming the formation of a TA-Fe-P complex in the process.

Article Abstract

Phosphorus removal from wastewater is of great importance. In the present study, ferric chloride was selected as the coagulant, and tannic acid (TA), a natural polymer, as the coagulant aid to develop an effective coagulation process with the emphasis of phosphorus recovery from different types of wastewater. The results showed that TA can accelerate the settling speed by forming flocs with large size, reduce the residual Fe(III) to eliminate the yellow color caused by Fe(III), and slightly increase the phosphorus removal efficiency. The precipitate formed by TA-aided coagulation showed the advantage of releasing phosphorus faster than ferric phosphate, indicating the possibility of phosphorus recovery from wastewater as slow release fertilizer. To further understand the structural characteristics of the precipitate, analytical techniques such as Raman spectroscopy, X-ray photoelectron spectroscopy and matrix-assisted laser desorption ionization-time of flight mass spectrometry were employed. The analytical results indicated that TA-Fe-P complex was formed during the coagulation/flocculation processes. Solid phase in the precipitate consisted of TA-Fe-P complex, Fe-TA complex and/or ferric hydroxyphosphate.

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http://dx.doi.org/10.1016/j.chemosphere.2008.02.028DOI Listing

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