The effect of electric and magnetic fields on the sandwich structure Pt/hydrogenated amorphous silicon (a-Si:H)/stearic acid monolayer/Langmuir-Blodgett film of Ag/Co nanoparticles encapsulated in an organic envelope is studied. This structure is used as a working electrode in an electrochemical cell filled with NaCl solution (1 mM) and equipped with an Ag/AgCl reference electrode. Reversible changes in voltammograms are observed due to treatments (negative or positive bias voltage and simultaneous laser irradiation) applied to the designed structure before measurements. As an explanation of the observed phenomena we suggest that both the Co-up and Ag-up (on the a-Si:H surface) orientation orderings of nanoparticle Ag/Co cores are repeatedly reached. The role of the photovoltaic material (a-Si:H) in the observed behavior is explained. Voltammetric measurements with an applied magnetic field support our idea about the orientation ordering of nanoparticle cores.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1002/cphc.200700775 | DOI Listing |
Nanoscale
January 2025
Department of Materials Science, Institute of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan.
Pyrrole in a cholesteric liquid crystal was discharged using a Tesla coil to generate pyrrole radicals, affording linear-shaped nano-ordered pyrrole oligomers. Subsequently, the electrochemical polymerisation of a pre-oriented pyrrole oligomer having good affinity for liquid crystals was performed to achieve polypyrrole-imprinted asymmetry from the cholesteric liquid crystal structure. The resultant polymers were analysed using polarising optical microscopy observations, scanning electron microscopy, electrochemistry, optical spectroscopy, and electron spin resonance.
View Article and Find Full Text PDFSyst Rev
January 2025
Big Data in Medicine, Carl von Ossietzky Universität Oldenburg, Ammerländer Heerstraße 114-118, 26129, Oldenburg, Germany.
Background: The implementation of computerised clinical decision support systems has the potential to enhance healthcare by improving patient safety, practitioner performance, and patient outcomes. Notwithstanding the numerous advantages, the uptake of clinical decision support systems remains constrained, thereby impeding the full realisation of their potential. To ensure the effective and successful implementation of these systems, it is essential to identify and analyse the reasons for their low uptake and adoption.
View Article and Find Full Text PDFSci Rep
January 2025
Laboratory for Mesoscopic Systems, Department of Materials, ETH Zurich, 8093, Zurich, Switzerland.
We present a study on nanoscale skyrmionic spin textures in [Formula: see text], a rare-earth complex noncollinear ferromagnet. We confirm, using X-ray microscopy, that [Formula: see text] can host lattices of metastable skyrmion bubbles at room temperature in the absence of a magnetic field, after applying a suitable field cooling protocol. The skyrmion bubbles are robust against temperature changes from room temperature to 330 K.
View Article and Find Full Text PDFSci Rep
January 2025
School of Spatial Planning and Design, Hangzhou City University, Hangzhou, 310015, China.
Marine climate significantly influences the spatial morphology of coastal village's streets. However, research on coastal villages lacks spatial parameterization analysis that can cope with the complex climatic environment. Focusing on the coastal village's street in Fuzhou City, China, this paper studies the relationship between street space morphology and the impact of extreme heat and wind conditions.
View Article and Find Full Text PDFSci Rep
January 2025
Department of ENT/Audiology & School for Mental Health and NeuroScience (MHENS), Maastricht University Medical Centre, Maastricht, The Netherlands.
Traditionally, the place-pitch 'tonotopically' organized auditory neural pathway was considered to be hard-wired. Cochlear implants restore hearing by arbitrarily mapping frequency-amplitude information. This study shows that recipients, after a long period of sound deprivation, preserve a level of auditory plasticity, enabling them to swiftly and concurrently learn speech understanding with two alternating, distinct frequency maps.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!