Orientation ordering of nanoparticle Ag/Co cores controlled by electric and magnetic fields.

Chemphyschem

Institute of Physics, Slovak Academy of Sciences, Dúbravská cesta 9, 845 11 Bratislava, Slovak Republic.

Published: May 2008

AI Article Synopsis

  • The study investigates how electric and magnetic fields affect a specific sandwich structure made of platinum, hydrogenated amorphous silicon, stearic acid, and silver/cobalt nanoparticles.
  • Reversible changes in the voltammograms indicate that treatments such as bias voltage and laser irradiation influence the orientation of the nanoparticles' cores.
  • The behavior is explained by the role of the photovoltaic material, hydrogenated amorphous silicon, and voltammetric measurements in a magnetic field confirm these orientation changes.

Article Abstract

The effect of electric and magnetic fields on the sandwich structure Pt/hydrogenated amorphous silicon (a-Si:H)/stearic acid monolayer/Langmuir-Blodgett film of Ag/Co nanoparticles encapsulated in an organic envelope is studied. This structure is used as a working electrode in an electrochemical cell filled with NaCl solution (1 mM) and equipped with an Ag/AgCl reference electrode. Reversible changes in voltammograms are observed due to treatments (negative or positive bias voltage and simultaneous laser irradiation) applied to the designed structure before measurements. As an explanation of the observed phenomena we suggest that both the Co-up and Ag-up (on the a-Si:H surface) orientation orderings of nanoparticle Ag/Co cores are repeatedly reached. The role of the photovoltaic material (a-Si:H) in the observed behavior is explained. Voltammetric measurements with an applied magnetic field support our idea about the orientation ordering of nanoparticle cores.

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http://dx.doi.org/10.1002/cphc.200700775DOI Listing

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