Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/anie.200705927 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Sb-to-P Metathesis: A Direct Route to Structurally Constrained, Cationic P Compound.
Angew Chem Int Ed Engl
November 2024
School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, 69978, Tel Aviv, Israel.
Structurally constrained, cationic P compound [LP][SbCl] with an OCO pincer-type ligand (L) having a central carbene donor was directly synthesized via an Sb-to-P metathesis reaction between PCl and LSb-Cl. [LP][SbCl] was isolated and its reactivity with small molecules (ROH and RNH) was studied, showing that [SbCl] is not an innocent counter anion, but an active participant in these reactions. When the [SbCl] was replaced with the [CBH] ([Cb]) anion, the reactions were redirected to [LP] cation only.
View Article and Find Full Text PDF(Electro)chemical N Splitting by a Molybdenum Complex with an Anionic PNP Pincer-Type Ligand.
ACS Org Inorg Au
June 2024
Georg-August-Universität Göttingen, Institut für Anorganische Chemie, Tammannstr. 4, Göttingen 37077, Germany.
Molybdenum(III) complexes bearing pincer-type ligands are well-known catalysts for N-to-NH reduction. We investigated herein the impact of an anionic PNP pincer-type ligand in a Mo(III) complex on the (electro)chemical N splitting ([MoCl], , H = 2,6-bis((di--butylphosphaneyl)methyl)-pyridin-4-one). The increased electron-donating properties of the anionic ligand should lead to a stronger degree of N activation.
View Article and Find Full Text PDFA "Pincer" Type of Acridine-Triazole Fluorescent Dye for Iodine Detection by Both 'Naked-Eye' Colorimetric and Fluorometric Modes.
Molecules
March 2024
Department of Brewing Engineering, Moutai Institute, Renhuai 564500, China.
Iodine, primarily in the form of iodide (I), is the bioavailable form for the thyroid in the human body. Both deficiency and excess intake of iodide can lead to serious health issues, such as thyroid disease. Selecting iodide ions among anions has been a significant challenge for decades due to interference from other anions.
View Article and Find Full Text PDFDirect synthesis of cyanate anion from dinitrogen catalysed by molybdenum complexes bearing pincer-type ligand.
Nat Commun
October 2022
Department of Applied Chemistry, School of Engineering, The University of Tokyo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Article Synopsis
- Dinitrogen is a valuable resource for creating organonitrogen compounds, which can reduce reliance on fossil fuels through direct synthesis under mild conditions.
- A molybdenum-carbamate complex was developed to facilitate the conversion of dinitrogen into cyanate anion (NCO) using ambient reaction conditions.
- The process involves a two-step synthetic cycle where samarium diiodide acts as a reductant, allowing the efficient formation of NCO from dinitrogen.
The tetrel bonding role in supramolecular aggregation of lead(II) acetate and a thiosemicarbazide derivative.
Acta Crystallogr B Struct Sci Cryst Eng Mater
August 2022
Advanced Materials for Industry and Biomedicine Laboratory, Kurgan State University, Sovetskaya Str. 63/4, 640020 Kurgan, Russian Federation.
A new Pb coordination complex [PbL(OAc)], which was readily synthesized from a mixture of Pb(OAc)·3HO and 1-(pyridin-2-yl)benzylidene-4-phenylthiosemicarbazide (HL) is reported. The crystal structure analysis of [PbL(OAc)] showed that the Pb cation is N,N',S-chelated by the tridentate pincer-type ligand L and by the oxygen atoms of the acetate anion. In addition, the metal centre forms Pb.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!