AI Article Synopsis

  • The study focuses on light scattering techniques for analyzing polydisperse spheroids, specifically using cellulosic nanowhiskers (CNW), by applying mathematical models within the Rayleigh-Gans-Debye limit.
  • Polydispersity indices were determined through fitting theoretical models to experimental data, resulting in length polydispersity of 2.3 and diameter polydispersities of 2.1 and 3.0 for samples treated with sulfuric and hydrochloric acids, respectively.
  • The results enabled the calculation of average dimensions for CNW, yielding lengths of 244 nm for hydrochloric acid and 272 nm for sulfuric acid, highlighting a new efficient methodology for characterizing

Article Abstract

Mathematical treatment of light scattering within the Rayleigh-Gans-Debye limit for spheroids with polydispersity in both length and diameter is developed and experimentally tested using cellulosic nanowhiskers (CNW). Polydispersity indices are obtained by fitting the theoretical formfactor to experimental data. Good agreement is achieved using a polydispersity of 2.3 for the length, independent of the type of acid used. Diameter polydispersities are 2.1 and 3.0 for sulfuric and hydrochloric acids, respectively. These polydispersities allow the determination of average dimensions from the z-average mean-square radius (z) and the weight-average molecular weight (M w) easily obtained from Berry plots. For cotton linter hydrolyzed by hydrochloric acid, the average length and diameter are 244 and 22 nm. This compares to average length and diameter of 272 and 13 nm for sulfuric acid. This study establishes a new light-scattering methodology as a quick and robust tool for size characterization of polydisperse spheroidal nanoparticles.

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Source
http://dx.doi.org/10.1021/bm7013137DOI Listing

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