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Catalyst self-adaptation in conjugate addition to nitroalkenes and nitroacrylates: instant chirality control in diphenylmethane-based phosphoramidite ligands. | LitMetric
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Catalyst self-adaptation in conjugate addition to nitroalkenes and nitroacrylates: instant chirality control in diphenylmethane-based phosphoramidite ligands.

Kazuki Wakabayashi Kohsuke Aikawa Susumu Kawauchi Koichi Mikami

J Am Chem Soc

Department of Applied Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan.

Published: April 2008

The tropos diphenylmethane-based phosphoramidite ligand (A) provides high catalytic activity and enantioselectivity in the Cu catalysis of conjugate addition to nitroalkenes and nitroacrylate, by virtue of instant chirality control in A.

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http://dx.doi.org/10.1021/ja710340nDOI Listing

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