Electromagnetically induced transparency is observed in a mismatched-wavelength cascade system with a room-temperature rubidium vapor cell. A cw probe laser beam monitors the 5S(1/2) ? 5P(3/2) transition while another cw laser couples the 5P(3/2) state to a higher excited state. The ratio of the observed Rabi frequencies for coupling to the 5P(3/2) ? 8D(3/2), (5/2) transitions agrees well with that predicted by use of the transition oscillator strengths. Optical switching is demonstrated with an 80-mW coupling laser beam modulated up to 1 MHz.
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http://dx.doi.org/10.1364/ao.40.002047 | DOI Listing |
J Chem Theory Comput
March 2025
Department of Chemistry, Chicago Center for Theoretical Chemistry, University of Chicago, Chicago, Illinois 60637, United States.
Single-molecule magnets (SMMs) are promising candidates for molecular-scale data storage and processing due to their strong magnetic anisotropy and long spin relaxation times. However, as the temperature rises, interactions between electronic states and lattice vibrations accelerate spin relaxation, significantly limiting their practical applications. Recently, ab initio simulations have made it possible to advance our understanding of phonon-induced magnetic relaxation, but significant deviations from the experiments have often been observed.
View Article and Find Full Text PDFAnal Chim Acta
May 2025
Department of Nephrology, The First Affiliated Hospital of Ningbo University, Ningbo, 315010, Zhejiang, PR China. Electronic address:
The sensitive, efficient, and simultaneous assay of creatinine and urea in different body fluid is crucial for the daily detection and treatment of chronic kidney disease. Here, we exploited a versatile composite surface enhanced Raman scattering (SERS) substrate of polydimethylsiloxane (PDMS)-flower-like ZIF-67@Ag nanoparticles (NPs) based on simple in-situ growth and ion sputtering strategies. The plasmonic Ag NPs assembled on the three-dimensional anisotropic ZIF-67 matrix, facilitating numerous resonant electromagnetic "hotspots".
View Article and Find Full Text PDFAnal Chim Acta
May 2025
College of Pharmacy, Guangdong Pharmaceutical University, Guangzhou Higher Education Mega Center, Guangzhou, 510006, PR China.
Background: Creatinine is a small molecule disease biomarker that reflects kidney function, accurate and effective detection of creatinine will play an important role in the prevention and treatment of diseases. Currently, commonly used creatinine detection methods are limited by expensive instruments, complex sample preparation, many interference factors from biological samples, and environmental factors that can affect the accuracy of the measurement. Therefore, developing a fast, simple, inexpensive, sensitive analysis method that can eliminate background interference and provide multi-detection modes has strong attraction and value.
View Article and Find Full Text PDFMicrobes Environ
March 2025
Faculty of Science, Kagoshima University.
Frankia spp. are multicellular actinobacteria with the ability to fix atmospheric dinitrogen (N). Frankia fixes N not only in the free-living state, but also in root-nodule symbioses with more than 200 plant species called actinorhizal plants.
View Article and Find Full Text PDFNanomicro Lett
March 2025
Key Laboratory of Hydraulic Machinery Transients, Ministry of Education, School of Power and Mechanical Engineering, Wuhan University, Wuhan, 430072, People's Republic of China.
Elevating the upper cutoff voltage to 4.6 V could effectively increase the reversible capacity of LiCoO (LCO) cathode, whereas the irreversible structural transition, unstable electrode/electrolyte interface and potentially induced safety hazards severely hinder its industrial application. Building a robust cathode/electrolyte interface film by electrolyte engineering is one of the efficient approaches to boost the performance of high-voltage LCO (HV-LCO); however, the elusive interfacial chemistry poses substantial challenges to the rational design of highly compatible electrolytes.
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