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We analyze the effects of both bond and potential disorder in the vicinity of a first-order metal insulator transition in a two-band model for manganites using a real-space Monte Carlo method. Our results reveal a novel charge-ordered state coexisting with spin-glass behavior. We provide the basis for understanding the phase diagrams of half-doped manganites, and contrast the effects of bond and potential disorder and the combination of both.
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http://dx.doi.org/10.1103/PhysRevLett.100.076406 | DOI Listing |
Biosens Bioelectron
December 2024
School of Medical Science and Technology, Indian Institute of Technology, Kharagpur, 721302, West Bengal, India. Electronic address:
Monitoring HO levels in live cells is essential due to its superior stability and possible severity inside the cell. The quest for a superior platform capable of detecting cellular-level hydrogen peroxide (HO) concentrations without necessitating the use of high-cost enzymes is of utmost importance. Here, the quantification of intracellular HO concentrations has been performed using silver metal polymer-based nonenzymatic electrochemical detection.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
Key Laboratory of Radiation Physics and Technology, Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, No. 24 South Section 1, Yihuan Road, 610065 Chengdu, People's Republic of China.
Obtaining effective extreme ultraviolet lithography (EUVL) materials for pragmatic applications remains challenging. The experimental design and conventional theoretical prediction are time-consuming and costly and hardly affordable to accelerate the discovery of commercial EUVL materials. In this work, we employed the machine learning (ML) technique to predict the ionization potential of promising EUVL materials, which is closely related to the photoresists' solubility switch.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Chinese Academy of Sciences Fujian Institute of Research on the Structure of Matter, The State Key Laboratory of Structural Chemistry, 155 Yangqiao Road West, 350002, Fuzhou, CHINA.
Macrocycles represent one important class of functional molecules, and dynamic macrocycles with the potential of cleavability, adaptability, and topological conversion are challenging. Herein we report photoswitchable allosteric and topological control of dynamic covalent macrocycles and further the use in guest binding and mechanically interlocked molecules. The manipulation of competing ring-chain equilibria and bond formation/scission within reaction systems enabled light-induced structural regulation over dithioacetal and thioacetal dynamic bonds, accordingly realizing bidirectional switching between crown ether-like covalent macrocycles and their linear counterparts.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Key Laboratory of Green Chemical Process of Ministry of Education, School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, PR China. Electronic address:
Employing metallic nanoclusters as cocatalysts for semiconductor-based photocatalysts and understanding their roles in enhancing photocatalytic performance is crucial. Herein, a nickel thiolate with cyclohexanethiol as the ligands (i.e.
View Article and Find Full Text PDFFront Nutr
December 2024
School of Pharmaceutical Science, Binzhou Medical University, Yantai, China.
Aim: This research aimed to probe the effects of fecal microbiota and on the metabolism of Radix Astragali (RA) and solid fermenting Radix Astragali (FRA). It further explores pharmacological effects of RA, , and FRA on HUA mouse model and the mechanisms in HUA treatment.
Methods: Fecal microbiota and were used to ferment FRA and RA in vitro to probe the impacts of microbiota on the metabolism of active compound.
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