Ag-TiO(2) nanocermet thin films, deposited for optical filtering applications by two sputtering techniques, codeposition and multilayer deposition, exhibit surface plasmon absorption in the spectral range 450-500 nm. The cosputtering technique induces a columnar growth, whereas multilayer deposition produces a more-random distribution of silver inclusions. Both films have large, flat silver grains at the air-cermet interface. An optical double-heterogeneous layer model based on the experimental morphological parameters of the films accounts well for their experimental transmittance, notably for extra absorption near 700 nm, which is attributed to a surface plasmon in the flat silver grains of the surface.
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Environ Sci Technol
January 2025
Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Kowloon, Hong Kong 999077, China.
Polyelectrolyte multilayer (PEM) membranes, with advantageous features of versatile chemistry and structures, are driving the development of advanced nanofiltration (NF) membranes with exceptional performance. While developing a printing method holds great promise for the eventual mass production of these membranes, reports on the printing method and the underlying mechanisms of membrane formation are currently scarce. Herein, we develop an aerosol-assisted printing (AAP) system for fabricating PEM NF membranes with highly tunable separation characteristics.
View Article and Find Full Text PDFSmall
January 2025
Department of Precision Instrument, Tsinghua University, Beijing, 100084, China.
The rapid development of flexible electronics necessitates simplified processes that integrate heterogeneous materials and structures. In this study, laser engraving is combined with electrochemical deposition (ECD) to directly fabricate various micro/nano-structured components and flexible electronic circuits. A theoretical framework and simulation model are developed to design the on-demand ECD on laser induced graphene (LIG), enabling the generation of multi-scale copper (Cu) materials with controllable oxidation states.
View Article and Find Full Text PDFNano Lett
January 2025
Department of Physics, Centre for Materials Science and Nanotechnology, University of Oslo, PO Box 1048 Blindern, N-0316 Oslo, Norway.
Polymorphism determines significant variations in materials' properties by lattice symmetry variation. If they are stacked together into multilayers, polymorphs may work as an alternative approach to the sequential deposition of layers with different chemical compositions. However, selective polymorph crystallization during conventional thin film synthesis is not trivial; changes of temperature or pressure when switching from one polymorph to another during synthesis may cause degradation of the structural quality.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Materials Engineering, Babol Noshirvani University of Technology, Mazandaran, Iran.
AISI 316L stainless steel is extensively used in various fields, including medicine. In this study, in order to improve antibacterial properties, reduce elastic modulus, increase hydrophilicity and delay corrosion on the surface of AISI 316L stainless steel pieces for biomedical applications, zinc and magnesium elements were used for coating. Zn monolayer, Zn-Mg bilayer, and Zn-Mg-Zn triple coatings were deposited on AISI 316L substrates using the thermal evaporation method.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Department of Physics, Changwon National University, Changwon 51140, Republic of Korea.
A mechanically robust flexible transparent conductor with high thermal and chemical stability was fabricated from welded silver nanowire networks (w-Ag-NWs) sandwiched between multilayer graphene (MLG) and polyimide (PI) films. By modifying the gas flow dynamics and surface chemistry of the Cu surface during graphene growth, a highly crystalline and uniform MLG film was obtained on the Cu foil, which was then directly coated on the Ag-NW networks to serve as a barrier material. It was found that the highly crystalline layers in the MLG film compensate for structural defects, thus forming a perfect barrier film to shield Ag NWs from oxidation and sulfurization.
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