Chemoselective hydrogenation of nitroarenes with carbon nanofiber-supported platinum and palladium nanoparticles.

Org Lett

Graduate School of Engineering Sciences, Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, Japan.

Published: April 2008

Platinum and palladium nanoparticles supported on three types of carbon nanofibers (CNFs) are synthesized and used as catalysts in the hydrogenation of nitroarenes. Nanosized platinum particles dispersed on platelet-type CNF efficiently catalyze the reduction of functionalized nitroarenes to the corresponding substituted anilines in high turnover numbers with other functional groups remaining intact.

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http://dx.doi.org/10.1021/ol800277aDOI Listing

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