AI Article Synopsis
- Large porphyrinoids containing three Rh(CO)2 groups at their dipyrrin units undergo a two-step metal transposition when dissolved in solution.
- The balance between the C3v-isomer and the Cs-isomer forms a dynamic equilibrium that is influenced by the polarity of the solvent.
- This study shows how the structural changes in these large molecules can be affected by their chemical environment, particularly the solvent used.
Article Abstract
Large porphyrinoids with three Rh(CO)2 groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C3v-isomer and the Cs-isomer depends on the solvent polarity.
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| http://dx.doi.org/10.1039/b717022j | DOI Listing |
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