We explore the effects of colloid shape on straining kinetics by measuring the filtration of spherical and nonspherical colloids within saturated columns packed with quartz sand. Our observations demonstrate that the transport of peanut-shaped colloids matches the transport of spherical colloids with diameters equal to the minor-axis length of the peanut-shaped colloids. The straining rates of the spherical colloids vary linearly with the ratio of colloid diameter (d(p)) to sand-grain diameter (d(g)) for 0.0083 < d(p)/d(g) < 0.06. This linear relationship also quantifies the straining rates of the peanut-shaped particles provided that the particle's minor axis length is used for d(p). Results of pore-scale simulations reveal that a peanut-shaped particle adopts a preferred orientation as it approaches a pore-space constriction such that its major axis tends to align with the local flow direction. The extent of this reorientation increases with the particle's aspect ratio. Findings from this research suggest that straining is sensitive to changes in colloid shape and thatthe kinetics of this process can be approximated on the basis of measurable properties of the nonspherical colloids and porous media.
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January 2025
Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Wendlingweg 2, 52074, Aachen, Germany.
Understanding and controlling the morphology of microgels is crucial for optimizing their properties and functions in diverse areas of application. The fabrication of microgels that exhibit both structural and chemical anisotropy using a template-free approach faces significant challenges. Existing approaches toward such microgels are typically limited to templating methods with low throughput.
View Article and Find Full Text PDFSoft Matter
January 2025
Department of Mechanical and Aerospace Engineering, University at Buffalo, Buffalo, NY 14260, USA.
Phys Rev E
October 2024
Institute for Solid State Physics and Optics, HUN-REN Wigner Research Centre for Physics, P.O. Box 49, H-1525 Budapest, Hungary.
J Phys Chem Lett
November 2024
Department of Physics, Jackson State University, Jackson, Mississippi 39217, United States.
Both absorption and emission of light in semiconductor quantum dots occur through excitation or recombination of confined electron-hole pairs, or excitons, with tunable size-dependent resonant frequencies that are ideal for applications in various fields. Some of these applications require control over quantum dot shape uniformity, while for others, control over energy splittings among exciton states emitting light in different polarizations and/or between bright and dark exciton states is of key importance. These splittings, known as exciton fine structure, are very sensitive to the nanocrystal shape.
View Article and Find Full Text PDFFood Chem
February 2025
School of Food Science and Engineering, Yangzhou University, Huayang Xilu 196, Yangzhou, Jiangsu 225127, People's Republic of China.
For the first time, curdlan (CL) was reported to have emulsifying property. Based on its emulsifying property and gelling property, the CL-based simple-structured emulsion gels were prepared. Among different CLs, CL-4 showed relatively good emulsifying property and its based emulsion showed the best stability, which might be mainly due to its highest hydrophobic property.
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