We studied the effect of changing temperature on the mechanical properties of nanosized poly(methyl methacrylate) wires fabricated by two-photon fabrication. At around room temperature, the nanowires showed a transition temperature where the shear modulus suddenly changed. This transition temperature was observed to decrease more than 40 K by decreasing the radius of the nanowires from 450 to 150 nm. This size is several times larger in nanowires than reported values of polymer thin film thickness showing a depression of the glass transition temperature.
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http://dx.doi.org/10.1021/jp800453p | DOI Listing |
Langmuir
January 2025
Institute for Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.
The amount of incorporation of linear alcohols and ethers in HSiWO·6HO (HSiW·6HO, 50 wt %) supported on silica (SiO) was estimated by a conventional volumetric method and infrared (IR) spectroscopy, and the state of involved molecules was elucidated. First, the attribution of the key IR band at 2200 cm, which was observed for the water of crystallization of HSiW·6HO, to HO species (protons) was verified by coincident observation of thermogravimetric-differential thermal analysis, X-ray diffraction (XRD), and IR spectroscopy during thermal treatment in addition to the isotope exchange with DO. The 2200 cm band was gradually decreased in intensity by increasing the amount of adsorption of pyridine and was totally consumed at saturation, while the volumetric method provided the accurate number of included pyridine molecules.
View Article and Find Full Text PDFCancer immunotherapy using engineered cytotoxic effector cells has demonstrated significant potential. The limited spatial complexity of existing models, however, poses a challenge to mechanistic studies attempting to approve existing approaches of effector cell-mediated cytotoxicity within a three-dimensional, solid tumor-like environment. To gain additional experimental control, we developed an approach for constructing three-dimensional (3D) culture models using smart polymers that form temperature responsive hydrogels.
View Article and Find Full Text PDFSmall
January 2025
Department of Materials Science and Engineering, National Yang-Ming Chiao Tung University, Hsinchu, 30010, Taiwan.
Silver chalcogenides exhibit exceptional transport properties but face structural instability at high temperatures, limiting their practical applications. Using AgTe as a model, it is confirm that silver whisker growth above the phase transition renders AgTe unsuitable for thermoelectric applications. Here, the whisker growth mechanism is investigated and propose an inhibition strategy, overcoming a major obstacle in using silver chalcogenides.
View Article and Find Full Text PDFSci Rep
January 2025
Innovation Institute for Sustainable Maritime Architecture Research and Technology, Qingdao University of Technology, Qingdao, 266033, People's Republic of China.
During the hot summer months, the significant temperature disparity between outdoor and indoor air-conditioned spaces can lead to thermal discomfort and pose a potential health risk. Transition areas such as corridors and elevator lobbies, serving as intermediary zones connecting indoors and outdoors, have been found effective in mitigating this thermal discomfort. In this study, three different temperatures (25 °C-case 1, 27 °C-case 2, and 29 °C-case 3) were employed to investigate the dynamic physiological regulation and thermal perception response of individuals when transitioning from an outdoor environment into an indoor neutral room through a transition space.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physical Education, States University of Pará, Pará, Brazil.
It is well known that elite athletes of specific ethnicities and/or nationalities dominate certain sports disciplines (e.g., East Africans in marathon running).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!