Fast nuclear magnetic resonance correlation spectroscopy without diagonal peaks: the "2-1" correlation spectroscopy.

Rev Sci Instrum

Wuhan Center for Magnetic Resonance, State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, Wuhan 430071, People's Republic of China.

Published: February 2008

A fast NMR experiment is proposed for measuring correlation spectroscopy (COSY) spectra with diagonal peaks completely removed or largely suppressed. This new pulse sequence is based on double quantum spectroscopy but with delayed detection, so that the double quantum coherence is effectively transferred to single quantum coherence. Therefore, the pulse sequence can be named "2-1" COSY.

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Source
http://dx.doi.org/10.1063/1.2836264DOI Listing

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