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http://dx.doi.org/10.1126/science.1155093 | DOI Listing |
Brain Spine
October 2024
Department of Neurosurgery, University Hospital of Dijon Bourgogne, Dijon, France.
Introduction: The introduction of intraoperative fluorophores represented a significant advancement in neurosurgical practice. Nowadays they found different applications: in oncology to improve the visualization of tumoral tissue and optimize resection rates and in vascular neurosurgery to assess the exclusion of vascular malformations or the permeability of bypasses, with real-time intraoperative evaluations.
Research Question: A comprehensive knowledge of how fluorophores work is crucial to maximize their benefits and to incorporate them into daily neurosurgical practice.
Small
January 2025
Key Laboratory of Eco-chemical Engineering, International S&T Cooperation Foundation of Eco-chemical Engineering and Green Manufacture, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, P. R. China.
Crafting anisotropically epitaxial p-n heterostructures with Z-scheme charge transmission is a promising avenue toward excellent photocatalytic efficiency, yet the large lattice mismatch and diverse crystal growth habits between components have often arisen as a big challenge to this goal. Here, anisotropically epitaxial p-n heterostructures with 19.8% lattice mismatch are obtained via a dynamics-mediated seeded growth tactic under reaction temperature as low as 60 °C.
View Article and Find Full Text PDFAdv Mater
January 2025
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, P. R. China.
Biomimetic calcification is a micro-crystallization process that mimics the natural biomineralization process, where biomacromolecules regulate the formation of inorganic minerals. In this study, it is presented that a protein-assisted biomimetic calcification method for the in situ synthesis of nitrogen-doped metal-organic framework (MOF) materials. A series of unique core-shell structures are created by utilizing proteins as templates and guiding agents in the nucleation step, creating ideal conditions for shell growth.
View Article and Find Full Text PDFChemistry
January 2025
Department of Inorganic Chemistry, University of Regensburg, Universitätsstraße 31, 93053, Regensburg, Germany.
The systematic nucleophilic functionalization of the cationic pentaphosphole ligand complex [Cp*Fe(η-PMe)][OTf] (A) with group 16/17 nucleophiles is reported. This method represents a highly reliable and versatile strategy for the design of novel transition-metal complexes featuring twofold substituted end-deck cyclo-P ligands, bearing unprecedented hetero-element substituents. By the reaction of A with classical group 16 nucleophiles, complexes of the type [Cp*Fe(η-PMeE)] (E=OEt (1), OBu (2), SPh (3), SePh (4)) are obtained.
View Article and Find Full Text PDFEnviron Monit Assess
January 2025
Taywade College, Koradi, Nagpur, Maharashtra, 441111, India.
Coastal waters are the ultimate destination for both point and non-point sources of contamination. The uncontrolled dicharge of fecal waste into the ocean harms natural resources, marine life, and poses health risks to humans. Regular monitoring of coastal water quality and source tracking is important to prevent disease outbreaks.
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