Excitation-emission matrix spectroscopy (EEMS) was used to characterize the ultra violet fluorescence fingerprints of eight crude oils (with a 14,470-fold range of dynamic viscosity) in seawater. When the chemical dispersant Corexit 9500 was mixed with the oils prior to their dispersion in seawater, the fingerprints of each oil changed primarily as an increase in fluorescence over an emission band centered on 445 nm. In order to simplify the wealth of information available in the excitation-emission matrix spectra (EEMs), two ratios were calculated. A 66-90% decrease in the slope ratio was observed with the addition of Corexit. When the slope ratios were reduced in complexity to intensity ratios, similar trends were apparent. As a result either of the ratios could be used as a simple and rapid means of identifying and monitoring chemically dispersed oil in the open ocean.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.marpolbul.2007.12.022 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Spectral and molecular insights into the variations of dissolved organic matter in shallow groundwater impacted by surface water recharge.
Water Res
December 2024
State Key Laboratory of Environmental Criteria and Risk Assessment, and State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
Dissolved organic matter (DOM) represents one of the most active elements in aquatic systems, whose fraction is engaged in chemical and biological reactions. However, fluorescence, molecular diversity and variations of DOM in groundwater systems with the alteration of surface water recharge remain unclear. Herein, Excitation-emission matrix (EEM) fluorescence spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) combined with principal component coefficients, parallel factor analyses (PARAFAC) with two‒dimensional correlation spectroscopy (2D-COS) were applied in this study.
View Article and Find Full Text PDFBehavior of compounds leached from tire tread particles under simulated sunlight exposure.
Water Res
December 2024
Department of Civil, Construction, and Environmental Engineering, San Diego State University, San Diego, CA 92182, USA. Electronic address:
Tire tread particles are microplastics (< 5 mm) and leach organic chemicals into aquatic environments. It is important to understand the behavior of tire wear compounds in sunlight-exposed waters in terms of their persistence, removal, and transformation. Therefore, we conducted photolysis experiments with leachates from laboratory-generated tire tread particles (TTP) over 72 h in a solar simulator to evaluate the behavior of leached compounds and fluorescent components over time.
View Article and Find Full Text PDFThe abiologically and biologically driving effects on organic matter in marginal seas revealed by deep learning-assisted model analysis.
Sci Total Environ
January 2025
Key Laboratory of Coastal Biology and Biological Resource Utilization, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China; University of Chinese Academy of Sciences, Beijing 101408, China. Electronic address:
The biogeochemical processes of organic matter exhibit notable variability and unpredictability in marginal seas. In this study, the abiologically and biologically driving effects on particulate organic matter (POM) and dissolved organic matter (DOM) were investigated in the Yellow Sea and Bohai Sea of China, by introducing the cutting-edge network inference tool of deep learning. The concentration of particulate organic carbon (POC) was determined to characterize the status of POM, and the fractions and fluorescent properties of DOM were identified through 3D excitation-emission-matrix spectra (3D-EEM) combined parallel factor analysis (PARAFAC).
View Article and Find Full Text PDFFluorescence excitation-emission matrix spectroscopy combined with machine learning for the classification of viruses for respiratory infections.
Talanta
December 2024
State Key Laboratory of NBC Protection for Civilian, Beijing, 102205, China. Electronic address:
Significant efforts were currently being made worldwide to develop a tool capable of distinguishing between various harmful viruses through simple analysis. In this study, we utilized fluorescence excitation-emission matrix (EEM) spectroscopy as a rapid and specific tool with high sensitivity, employing a straightforward methodological approach to identify spectral differences between samples of respiratory infection viruses. To achieve this goal, the fluorescence EEM spectral data from eight virus samples was divided into training and test sets, which were then analyzed using random forest and support vector machine classification models.
View Article and Find Full Text PDFExploring Distinct Second-Order Data Approaches for Thiamine Quantification via Carbon Dot/Silver Nanoparticle FRET Reversion.
Biosensors (Basel)
December 2024
LAQV, REQUIMTE, Department of Chemical Sciences, Laboratory of Applied Chemistry, Faculty of Pharmacy, University of Porto, Rua de Jorge Viterbo Ferreira n° 228, 4050-313 Porto, Portugal.
Accurate and selective monitoring of thiamine levels in multivitamin supplements is essential for preventing deficiencies and ensuring product quality. To achieve this, a Förster resonance energy transfer (FRET) system using carbon dots (CDs) as energy donors and citrate-stabilized silver nanoparticles (AgNPs) as energy acceptors was developed. The aqueous synthesis of AgNPs using microwave irradiation was optimized to obtain efficient plasmonic nanoparticles for FRET applications, targeting maximal absorbance intensity, stability, and wavelength alignment.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!