[Zn(H2O)4][Zn2Sn3Se9(MeNH2)] has an open polar framework based on supertetrahedral clusters with a unique double connectivity mode and exhibits a strong second harmonic generation response, excellent acid stability and proton exchange capacity.
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[Zn(H2O)4][Zn2Sn3Se9(MeNH2)]: a robust open framework chalcogenide with a large nonlinear optical response.
Chem Commun (Camb)
February 2008
Department of Chemistry, 2145 Sheridan Road, Northwestern University, Evanston, IL 60208-3113, USA.
[Zn(H2O)4][Zn2Sn3Se9(MeNH2)] has an open polar framework based on supertetrahedral clusters with a unique double connectivity mode and exhibits a strong second harmonic generation response, excellent acid stability and proton exchange capacity.
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