We investigated the growth mechanism of layered single-walled carbon nanotube (SWNT) mats by a cutting method. Transmission electron microscope observations revealed that new SWNTs grown below first grown SWNTs also have caps at their tips. Raman spectroscopy suggests that the SWNTs in each layer have the same chirality distribution. This growth method might be a way to prove a factor of chirality selection of SWNTs.
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http://dx.doi.org/10.1021/nl073119f | DOI Listing |
Nanomaterials (Basel)
December 2024
Centre for Advanced Material Application (CEMEA), Slovak Academy of Sciences, Dúbravská Cesta 5807/9, 845 11 Bratislava, Slovakia.
Single-walled carbon nanotubes [...
View Article and Find Full Text PDFBiosensors (Basel)
December 2024
Department of Gyedang College of General Education, Sangmyung University, 31 Sangmyungdae-Gil, Dongnam-Gu, Cheonan 31066, Republic of Korea.
The evolution of high-performance electrode materials has significantly impacted the development of real-time monitoring biosensors, emphasizing the need for compatibility with biomaterials and robust electrochemical properties. This work focuses on creating electrode materials utilizing single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs), specifically examining their dispersion behavior and electrochemical characteristics. By using ultrasonic waves, we analyzed the dispersion of CNTs in various solvents, including N, N-dimethylformamide (DMF), deionized water (DW), ethanol, and acetone.
View Article and Find Full Text PDFACS Nano
December 2024
Department of Mechanical Engineering, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan.
The intrinsic temperature dependence of Raman-active modes in carbon nanotubes (CNTs), particularly the radial breathing mode (RBM), has been a topic of a long-standing controversy. In this study, we prepared suspended individual CNTs to investigate how their Raman spectra depend on temperature and to understand the effects of environmental conditions on this dependency. We analyzed the intrinsic temperature dependence of the main Raman-active modes, including the RBM, the moiré-activated R feature, and the G-band in double-walled carbon nanotubes (DWCNT) and single-walled carbon nanotubes (SWCNTs) after complete desorption of air.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Air Force Research Laboratory, 711th Human Performance Wing, Wright-Patterson Air Force Base, Wright-Patterson AFB, Ohio 45433, United States.
Peptides, due to their diverse and controllable properties, are used as both liquid and gas phase recognition elements for both biological and chemical targets. While it is well understood how binding of a peptide to a biomolecule can be converted into a sensing event, there is not the same mechanistic level of understanding with regard to how peptides modulate the selectivity of semiconductor/conductor-based gas sensors. Notably, a rational, mechanistic study has not yet been performed to correlate peptide properties to the sensor response for volatile organic compounds (VOCs) as a function of chemical properties.
View Article and Find Full Text PDFHigh-performance infrared light sources have significantly influenced the fields of photonics and optoelectronics. However, achieving infrared light emission with low energy consumption, high brightness, and rapid response remains a huge challenge. Single-walled carbon nanotubes (SWCNTs) could be an important candidate for infrared light emitters because of their superior electron mobility and phonon transport efficiency.
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