AI Article Synopsis
- A new method has been developed to efficiently create different types of paracyclophanes that include a sulfur-based functional group.
- The main step in this process involves a substitution reaction facilitated by a sulfonium salt.
- This technique also showed promise in sulfenate salt chemistry, demonstrating an interesting phenomenon of chirality transfer.
Article Abstract
A straightforward and high-yielding access to various [2.2]paracyclophanes possessing a sulfur-based functional group is reported, the key step being a SEAr reaction mediated by a sulfonium salt. The versatility of the methodology was exemplified by an original application in sulfenate salt chemistry, from which a remarkable chirality transfer was observed.
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| http://dx.doi.org/10.1021/ol800161m | DOI Listing |
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