An anomalous photovoltaic film formed by simultaneous oblique sputter deposition of CdTe and CdS from different directions was integrated onto LiNbO(3) and combined with a Mach-Zehnder-type interferometric waveguide modulator. Irradiation by 830-nm laser light with low intensity near 1 mW of the photovoltaic film induced anomalous photovoltages of ~5 V, which is as high as the half-wave voltage. This photovoltage was used to control the signal light in the waveguide. Modulation by external light was demonstrated with a response time of 0.1 s. Because of the presence of CdS with a photoconductive effect, the response time was much faster than that of conventional anomalous photovoltaic films formed by oblique deposition of CdTe.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1364/ao.36.007870 | DOI Listing |
Adv Sci (Weinh)
January 2025
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China.
Circularly Polarized Light (CPL)-dependent anomalous photovoltaic effect (APVE), characterized by light helicity-manipulated steady photocurrent and above-bandgap photovoltage, has demonstrated significant potential in the fields of photoelectronic and photovoltaics. However, exploiting CPL-dependent APVE in chiral hybrid perovskites, a promising family with intrinsic chiroptical activity and non-centrosymmetric structure, remains challenging. Here, leveraging the flexible structural design of chiral alternating cations intercalation-type perovskites, CPL-dependent APV, for the first time, is achieved in chiral perovskites.
View Article and Find Full Text PDFNat Commun
January 2025
International Centre for Quantum Materials, Collaborative Innovation Centre of Quantum Matter, Peking University, Beijing, China.
The anomalous photovoltaic effect (APE) in polar crystals is a promising avenue for overcoming the energy conversion efficiency limits of conventional photoelectric devices utilizing p-n junction architectures. To facilitate effective photocarrier separation and enhance the APE, polar materials need to be thinned down to maximize the depolarization field. Here, we demonstrate Janus MoSSe monolayers (~0.
View Article and Find Full Text PDFThe intermediate phase produced by the complexation of metal ions and solvent molecules usually occurs in the crystallization process of perovskite single crystal or film. Effective monitoring of intermediate-phase evolution is beneficial to the control of crystal quality. However, it is difficult to realize.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2024
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315200, China.
Spatially resolved photoluminescence (PL) and electroluminescence (EL) imaging technologies play a crucial role in evaluating the performance and stability of photovoltaic devices. However, their application in perovskite devices presents unique challenges. In this study, we report a discrepancy between the electrical performance of perovskite solar modules (PSMs) and the EL images.
View Article and Find Full Text PDFACS Photonics
July 2024
Departamento de Física de Materiales, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
LiNbO is a distinguished multifunctional material where ferroelectric domain engineering is of paramount importance. This degree of freedom of the spontaneous polarization remarkably enhances the applicability of LiNbO, for instance, in photonics. In this work, we report the first method for all-optical domain inversion of LiNbO crystals using continuous-wave visible light.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!