We describe the synthesis, structure and magnetic properties of two decanuclear Fe(III) complexes with novel core topologies, assembled using the tetra-deprotonated form of Bis-tris {2-[bis(2-hydroxyethyl)amino]-2-(hydroxymethyl)propane-1,3-diol, H5L}.
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http://dx.doi.org/10.1039/b715932c | DOI Listing |
J Colloid Interface Sci
January 2025
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, College of Chemistry and Materials Science, College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004 PR China. Electronic address:
Low-cost and effective electrocatalysts are critical for energy storage and conversion. Herein, iron(III) and vanadium(III) acetylacetonates were first adsorbed and confined in porous zeolitic imidazolate framework-8 (ZIF-8), which further cross-linked together by the methanol-induced-assembly. Following the pyrolysis, the FeVO nanoparticles were efficiently encapsulated within three-dimensional (3D) N-doped interconnected porous carbon, termed FeVO/NIPC.
View Article and Find Full Text PDFActa Crystallogr C Struct Chem
December 2024
University of Melbourne, School of Chemistry, Grattan Street, Parkville, 3052, Australia.
Dalton Trans
December 2024
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region 142432, Russia.
ACS Omega
October 2024
Centro de Investigación en Servicios Químicos y Microbiológicos (CEQIATEC), Escuela de Química, Instituto Tecnológico de Costa Rica, Cartago 159-7050, Costa Rica.
Heliyon
August 2024
Geomicrobiology, Department of Geosciences, University of Tübingen, Schnarrenbergstrasse 94-96, 72076 Tübingen, Germany.
Nitrogen (N) fertilization in paddy soils decreases arsenic mobility and methane emissions. However, it is unknown how quantity and frequency of N fertilization affects the interlinked redox reactions of iron(II)-driven denitrification, iron mineral (trans-)formation with subsequent arsenic (im-)mobilization, methane and nitrous oxide emissions, and how this links to microbiome composition. Thus, we incubated paddy soil from Vercelli, Italy, over 129 days and applied nitrate fertilizer at different concentrations (control: 0, low: ∼35, medium: ∼100, high: ∼200 mg N kg soil) once at the beginning and after 49 days.
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