Intermolecular Cope-type hydroamination of alkynes using hydrazines.

Chem Commun (Camb)

Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, Ottawa, ON, Canada.

Published: January 2008

Metal-free, intermolecular hydroaminations are performed upon heating aryl acetylenes and MeNHNH(2) at 140 degrees C, with preferential formation of the linear, "anti-Markovnikov" hydrazones.

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Source
http://dx.doi.org/10.1039/b715022aDOI Listing

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