Xantphos as an efficient ligand for palladium-catalyzed cross-coupling reactions of aryl bromides and triflates with allyl acetates and indium.

J Org Chem

National Research Laboratory for Catalytic Organic Reaction, Department of Chemistry, and Institute for Basic Science, Kangwon National University, Chunchon 200-701, Republic of Korea.

Published: February 2008

AI Article Synopsis

Article Abstract

Xantphos was found to be an efficient ligand for palladium-catalyzed allyl cross-coupling reactions of aryl bromides and triflates with allylindium reagents generated in situ from allyl acetates and indium. These reactions occur in high yield with good functional group tolerance.

Download full-text PDF

Source
http://dx.doi.org/10.1021/jo702279tDOI Listing

Publication Analysis

Top Keywords

xantphos efficient
8
efficient ligand
8
ligand palladium-catalyzed
8
cross-coupling reactions
8
reactions aryl
8
aryl bromides
8
bromides triflates
8
allyl acetates
8
acetates indium
8
palladium-catalyzed cross-coupling
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!