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Doping-induced structure variation of 1,3-cyclohexane- bis(methylamine)-templated zinc-phosphorus open structures. | LitMetric
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Doping-induced structure variation of 1,3-cyclohexane- bis(methylamine)-templated zinc-phosphorus open structures.

Yang Yang Yongnan Zhao Jianguo Yu Shizhen Wu Ruji Wang

Inorg Chem

Institute of Nanostructured Materials, College of Materials Science and Chemical Engineering and Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University, Tianjin 300160, China.

Published: February 2008

By using 1,3-cyclohexane-bis(methylamine) (CHBMA) as the template, a novel zinc phosphatophosphite (TJPU-3) with extra-large 20-ring channels was synthesized. Cobalt doping produced a bimetallic phosphite (TJPU-6) with 12-ring apertures. While the templates sit in the cis configuration in TJPU-3, they are in the trans configuration in TJPU-6. This result has the potential for separation and recognition of CHBMA isomers.

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http://dx.doi.org/10.1021/ic701825mDOI Listing

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