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In situ hybridization of LiNH2-LiH-Mg(BH4)2 nano-composites: intermediate and optimized hydrogenation properties.
Phys Chem Chem Phys
February 2012
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Nano-composites of LiNH(2)-LiH-xMg(BH(4))(2) (0 ≤ x ≤ 2) were prepared by plasma metal reaction followed by a nucleation growth method. Highly reactive LiNH(2)-LiH hollow nanoparticles offered a favorable nucleus during a precipitation process of liquid Mg(BH(4))(2)·OEt(2). The electron microscopy results suggested that more than 90% of the obtained nano-composites were in the range 200-400 nm.
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Ford Motor Company, Research and Advanced Engineering, MD 1170/RIC, P.O. Box 2053, Dearborn, MI 48121, USA.
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