6,6'-(B10H13)2O with [Pt(cod)Cl2] gives the [(B10H13OB10H11)Pt-{(B10H10OB10H12)]2- anion in which, uniquely, the units are held together by a B-O-B linkage in combination with a B-B linkage; with [PtMe2(PMe2Ph)2] it gives [(PMe2Ph)2PtB10H10-O,H-B10H11Pt(PMe2Ph)] in which, uniquely, the units are held together by an unsupported hydrogen-to-metal linkage as well as a B-O-B linkage.
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