AI Article Synopsis
- The dissolution of the mononuclear complex [Zn(dmpzdtc)2] in BrCH2CH2Br or DMF with water resulted in the elimination of CS2.
- This process produced two distinct high-nuclearity metallamacrocyclic complexes.
- The complexes formed are [Zn4(micro-dmpz)6(micro-OH)2]2 and [Zn4(micro-dmpz)6(micro-OH)2]4, indicating different nuclearities.
Article Abstract
Dissolution of a mononuclear complex [Zn(dmpzdtc)2] in BrCH2CH2Br or DMF saturated with water followed by CS2 elimination led to the formation of two unique high-nuclearity metallamacrocyclic complexes, [Zn4(micro-dmpz)6(micro-OH)2]2 and [Zn4(micro-dmpz)6(micro-OH)2]4.
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| http://dx.doi.org/10.1039/b710787k | DOI Listing |
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