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Access to well-defined isolated Fe(II) centers on silica and their use in oxidation. | LitMetric

Access to well-defined isolated Fe(II) centers on silica and their use in oxidation.

Dalton Trans

Laboratoire de Chimie Organometallique de Surface, CPE Lyon 43 Bd du 11 Novembre 1918, F-69616 Villeurbanne Cedex, France.

Published: December 2007

Well-defined Fe(II) isolated sites are obtained by reaction of diaryl-N,N'-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO(2-(700)). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H(2)O(2).

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Source
http://dx.doi.org/10.1039/b711015dDOI Listing

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